全文获取类型
收费全文 | 1966篇 |
免费 | 49篇 |
国内免费 | 116篇 |
专业分类
化学 | 1210篇 |
晶体学 | 43篇 |
力学 | 29篇 |
综合类 | 29篇 |
数学 | 728篇 |
物理学 | 92篇 |
出版年
2023年 | 14篇 |
2022年 | 6篇 |
2021年 | 8篇 |
2020年 | 26篇 |
2019年 | 29篇 |
2018年 | 26篇 |
2017年 | 38篇 |
2016年 | 22篇 |
2015年 | 19篇 |
2014年 | 58篇 |
2013年 | 142篇 |
2012年 | 64篇 |
2011年 | 119篇 |
2010年 | 128篇 |
2009年 | 119篇 |
2008年 | 128篇 |
2007年 | 136篇 |
2006年 | 129篇 |
2005年 | 146篇 |
2004年 | 135篇 |
2003年 | 113篇 |
2002年 | 64篇 |
2001年 | 30篇 |
2000年 | 52篇 |
1999年 | 34篇 |
1998年 | 34篇 |
1997年 | 25篇 |
1996年 | 45篇 |
1995年 | 33篇 |
1994年 | 44篇 |
1993年 | 29篇 |
1992年 | 26篇 |
1991年 | 11篇 |
1990年 | 7篇 |
1989年 | 11篇 |
1988年 | 15篇 |
1987年 | 11篇 |
1986年 | 8篇 |
1985年 | 5篇 |
1984年 | 5篇 |
1982年 | 6篇 |
1981年 | 4篇 |
1980年 | 7篇 |
1979年 | 7篇 |
1978年 | 4篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有2131条查询结果,搜索用时 228 毫秒
1.
Li‐Na Wang Zhen‐Xun Zhou Dr. Xiao‐Na Li Dr. Tong‐Mei Ma Prof. Sheng‐Gui He 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(18):6957-6961
In addition to generation of a methyl radical, formation of a formaldehyde molecule was observed in the thermal reaction of methane with AuNbO3+ heteronuclear oxide cluster cations. The clusters were prepared by laser ablation and mass‐selected to react with CH4 in an ion‐trap reactor under thermal collision conditions. The reaction was studied by mass spectrometry and DFT calculations. The latter indicated that the gold atom promotes formaldehyde formation through transformation of an Au?O bond into an Au?Nb bond during the reaction. 相似文献
2.
Martien A. Würdemann Cristina Niţu Dr. Stefaan M. A. De Wildeman Dr. Katrien V. Bernaerts Prof. Dr. Romano V. A. Orru 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(36):8090-8100
Pyrazines are an underreported class of N-heterocycles available from nitrogen-rich biomass presenting an interesting functional alternative for current aromatics. In this work, access to pyrazines obtained from amino acids by using the 90 year old Dakin–West reaction was explored. After a qualitative screening several functional proteinogenic amino acids proved good substrates for this reaction, which were successfully scaled to multigram scale synthesis of the corresponding intermediate α-acetamido ketones. Subsequently, the conditions towards pyrazine formation using δ-amino-levulinic acid were optimized, and these were employed to synthesize a relevant set of five functional dimethylpyrazines in high purity. These pyrazines can be considered a versatile toolbox of aromatic building blocks for a wide range of applications, such as in the synthesis of polymers or metal–organic frameworks. 相似文献
3.
利用同余式、平方剩余、Pell方程的解的性质、递归序列证明了:不定方程x3-1=749y2仅有整数解(x,y)=(1,0). 相似文献
4.
Muharem Avdispahi 《Mathematische Nachrichten》2019,292(4):691-693
We correct the exponent in the error term of the prime geodesic theorem for hyperbolic 3‐manifolds 1 and in Park's theorem for higher dimensions [ 3 , 2 ]. 相似文献
5.
6.
Balasubramanian Sridhar Jagadeesh Babu Nanubolu Krishnan Ravikumar 《Acta Crystallographica. Section C, Structural Chemistry》2015,71(2):128-135
A new polymorph of cytosine, C4H5N3O, is reported half a century after the report of its first known crystal structure [Barker & Marsh (1964). Acta Cryst. 17 , 1581–1587]. Cytosine thus provides the first polymorphic example in the category of parent nucleobases. The new form, denoted (Ib), was observed unexpectedly during an attempt to cocrystallize cytosine with catechol. Form (Ib) crystallizes in the orthorhombic centrosymmetric space group Pccn with two molecules in the asymmetric unit. The previously known form, denoted (Ia), crystallizes in the orthorhombic noncentrosymmetric space group P212121. The cytosine molecule is planar in both forms. Hydrogen‐bonding interactions are also similar for both forms. Infinite one‐dimensional ribbons composed of cytosine base‐pair dimers in R22(8) arrangements are observed in both (Ia) and (Ib). However, the way that the ribbons are packed differs in (Ia) and (Ib). This appears to guide the centrosymmetric versus noncentrosymmetric space‐group selection through the formation of an inversion‐related motif in polymorph (Ib) and a helical propagation in polymorph (Ia). A few selected polymorphic systems have been gathered from the Cambridge Structural Database to understand possible structural features responsible for achiral molecules adopting centro‐ and noncentrosymmetric space groups. 相似文献
7.
8.
Firoz Firozzaman Fahim Firoz 《International Journal of Mathematical Education in Science & Technology》2017,48(5):756-762
Understanding the solution of a problem may require the reader to have background knowledge on the subject. For instance, finding an integer which, when divided by a nonzero integer leaves a remainder; but when divided by another nonzero integer may leave a different remainder. To find a smallest positive integer or a set of integers following the given conditions, one may need to understand the concept of modulo arithmetic in number theory. The Chinese Remainder Theorem is a known method to solve these types of problems using modulo arithmetic. In this paper, an efficient remainder rule has been proposed based on basic mathematical concepts. These core concepts are as follows: basic remainder rules of divisions, linear equation in slope intercept form, arithmetic progression and the use of a graphing calculator. These are easily understood by students who have taken prealgebra or intermediate algebra. 相似文献
9.
Assume a fixed point v∈VG can be separated from zero by a homogeneous invariant f∈𝕜[V]G of degree prd, where p>0 is the characteristic of the ground field 𝕜 and p,d are coprime. We show that then v can also be separated from zero by an invariant of degree pr, which we obtain explicitly from f. It follows that the minimal degree of a homogeneous invariant separating v from zero is a p-power. 相似文献
10.
Shai Sarussi 《代数通讯》2017,45(1):411-419
Let T be a totally ordered set and let D(T) denotes the set of all cuts of T. We prove the existence of a discrete valuation domain Ov such that T is order isomorphic to two special subsets of Spec(Ov). We prove that if A is a ring (not necessarily commutative), whose prime spectrum is totally ordered and satisfies (K2), then there exists a totally ordered set U?Spec(A) such that the prime spectrum of A is order isomorphic to D(U). We also present equivalent conditions for a totally ordered set to be a Dedekind totally ordered set. At the end, we present an algebraic geometry point of view. 相似文献